metal organic frameworks mofs for environmental applications

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Metal-Organic Frameworks (MOFs) for Environmental Applications
Author : Sujit K. Ghosh
Publisher : Elsevier
Release Date : 2019-06-07
ISBN 10 : 0128146346
Pages : 464 pages

Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. Examines the applications of metal-organic frameworks for the remediation of environmental pollutants Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China Explores possible solutions to some of today’s most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science

Elaboration And Applications Of Metal-organic Frameworks
Author : Ma Shengqian,Perman Jason A
Publisher : World Scientific
Release Date : 2018-01-29
ISBN 10 : 9813226749
Pages : 732 pages

Applications of Metal-Organic Frameworks and Their Derived Materials
Author : Inamuddin,Rajender Boddula,Mohd Imran Ahamed,Abdullah M. Asiri
Publisher : John Wiley & Sons
Release Date : 2020-06-10
ISBN 10 : 1119650984
Pages : 496 pages

Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

Photocatalytic Functional Materials for Environmental Remediation
Author : Alagarsamy Pandikumar,Kandasamy Jothivenkatachalam
Publisher : John Wiley & Sons
Release Date : 2019-07-11
ISBN 10 : 1119529840
Pages : 380 pages

A comprehensive volume on photocatalytic functional materials for environmental remediation As the need for removing large amounts of pollution and contamination in air, soil, and water grows, emerging technologies in the field of environmental remediation are of increasing importance. The use of photocatalysis—a green technology with enormous potential to resolve the issues related to environmental pollution—breaks down toxic organic compounds to mineralized products such as carbon dioxide and water. Due to their high performance, ease of fabrication, long-term stability, and low manufacturing costs, photofunctional materials constructed from nanocomposite materials hold great potential for environmental remediation. Photocatalytic Functional Materials for Environmental Remediation examines the development of high performance photofunctional materials for the treatment of environmental pollutants. This timely volume assembles and reviews a broad range of ideas from leading experts in fields of chemistry, physics, nanotechnology, materials science, and engineering. Precise, up-to-date chapters cover both the fundamentals and applications of photocatalytic functional materials. Semiconductor-metal nanocomposites, layered double hydroxides, metal-organic frameworks, polymer nanocomposites, and other photofunctional materials are examined in applications such as carbon dioxide reduction and organic pollutant degradation. Providing interdisciplinary focus to green technology materials for the treatment of environmental pollutants, this important work: Provides comprehensive coverage of various photocatalytic materials for environmental remediation useful for researchers and developers Encompasses both fundamental concepts and applied technology in the field Focuses on novel design and application of photocatalytic materials used for the removal of environmental contaminates and pollution Offers in-depth examination of highly topical green-technology solutions Presents an interdisciplinary approach to environmental remediation Photocatalytic Functional Materials for Environmental Remediation is a vital resource for researchers, engineers, and graduate students in the multi-disciplinary areas of chemistry, physics, nanotechnology, environmental science, materials science, and engineering related to photocatalytic environmental remediation.

Metal-Organic Frameworks
Author : Jianwen Jiang
Publisher : CRC Press
Release Date : 2015-01-28
ISBN 10 : 9814613460
Pages : 578 pages

Metal-organic frameworks (MOFs) have emerged as a new family of nanoporous materials. With an enormous choice of inorganic/organic building blocks, MOFs possess a wide range of surface area, pore size, and functionality and, thus, have been considered versatile materials for many potential applications. This book presents a broad collection of recent modeling studies in the field of MOFs toward potential engineering applications, such as gas storage/separation, carbon capture, catalysis, water purification, and drug delivery. The subject of this book renders it unique, for while the various topics on MOFs boast vast literature, there is not yet a single coherent collection for modeling endeavors. The book will appeal to scientists, engineers, and students in the multidisciplinary intersections of materials science, chemistry, and engineering.

Metal Organic Frameworks
Author : Victoria Samanidou,Eleni Deliyanni
Publisher : MDPI
Release Date : 2020-03-27
ISBN 10 : 303928486X
Pages : 198 pages

Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. Τhis is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.

Metal-Organic Frameworks
Author : David Farrusseng
Publisher : John Wiley & Sons
Release Date : 2011-09-19
ISBN 10 : 3527635866
Pages : 414 pages

An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future - Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification - Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks - Separation and purification of gases by MOFs - Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption - Manufacture of MOF thin films on structured supports for separation and catalysis - Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications - Separation of xylene isomers - Metal-Organic Frameworks as Catalysts for Organic Reactions - Biomedical applications of Metal Organic Frameworks - Metal Organic Frameworks for Biomedical Imaging - Luminescent Metal-Organic Frameworks - Deposition of thin films for sensor applications - Industrial MOF Synthesis - MOF shaping and immobilisation A must-have for every scientist in the field.

Metal-Organic Frameworks in Biomedical and Environmental Field
Author : Patricia Horcajada Cortés,Sara Rojas Macías
Publisher : Springer
Release Date : 2021-02-18
ISBN 10 : 9783030633790
Pages : 574 pages

This book joins an international and interdisciplinary group of leading experts on the biomedical, energy and environmental applications of Metal-Organic Frameworks (MOFs). The resulting overview covers everything from the environmentally friendly and scale up synthesis of MOFs, their application in green energy generation and storage, and water purification to their use as drug delivery systems, biosensors, and their association with relevant macromolecules (genes, enzymes). This book is focused on the interest of MOFs in applications such as the leading –edge environmental (energy-related) and biomedical fields. The potential of MOFs in these areas is currently progressing at a fast pace, since the wide possibilities that MOFs offer in terms of composition, topology, incorporation of active species (in their porosity, on their external surface or within the framework), and post-synthetic modifications, among others. The aim here is to provide future research goals that emphasize relevant nuances to this class of materials as a whole.

Metal-Organic Frameworks
Author : Leonard R. MacGillivray
Publisher : John Wiley & Sons
Release Date : 2010-12-17
ISBN 10 : 9781118035160
Pages : 349 pages

Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.

Metal-Organic Frameworks
Author : Fahmina Zafar,Eram Sharmin
Publisher : BoD – Books on Demand
Release Date : 2016-10-12
ISBN 10 : 9535126628
Pages : 166 pages

The emerging and interesting field of MOF encouraged us to bring forth the book titled ''Metal Organic Frameworks''. The book is divided into three sections. Section A consists of introduction, Section B comprises the synthesis and characterization techniques, and Section C is dedicated to the applications of MOFs. The book would be useful for scientists and researchers interested in the field of MOFs.

Metal-Organic Framework Composites
Author : Anish Khan
Publisher : Materials Research Forum LLC
Release Date : 2019-07-20
ISBN 10 : 1644900289
Pages : 286 pages

Composites based on Metal-organic frameworks (MOFs) have exceptional physical and chemical properties and offer a great number of advanced applications in such fields as energy storage, energy conversion by catalysis, sensors for environmental applications, environment safety and industrial wastewater treatments. They also have interesting medical applications, such as encapsulation of enzymes. The present book covers design, synthesis and preparation of various MOFs, as well as the resulting product characteristics: homogenous morphology, small size dispersion, high thermal stability and desired surface area.

Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare
Author : Alexander Samokhvalov
Publisher : CRC Press
Release Date : 2017-04-07
ISBN 10 : 1315350416
Pages : 216 pages

Adsorption and desorption in solution play significant roles in separations, detoxification of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicinal drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered 3-dimensional hybrid organic-inorganic polymers which contain metal cations and the structure-building organic "linker" units. Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable for adsorption and adsorption-based separations of large molecules of organic and bio-organic compounds. Thousands of organic compounds and, in particular, aromatic and heterocyclic compounds are widely used as feedstock for industrial chemical synthesis, as fine chemicals, major components of liquid fossil fuels, dyestuffs, industrial solvents, agricultural chemicals, medicinal drugs, pharmaceuticals and personal care products (PPCPs), and active pharmaceutical ingredients (APIs). There is a strong interest towards synthesis, characterization and studies of both known and newly synthesized mesoporous MOFs for adsorption in solution to achieve the high adsorption capacity, selectivity, and the possibility of multiple regeneration of "spent" sorbent. This book covers experimental fundamental research on using mesoporous MOFs in emerging applications of major industrial, environmental and academic importance, especially purification of water and liquid fossil fuels and in advanced biomedical technologies.

Metal-Organic Framework Composites
Author : Anish Khan
Publisher : Materials Research Forum LLC
Release Date : 2019-07-20
ISBN 10 : 1644900297
Pages : 282 pages

Composites based on Metal-organic frameworks (MOFs) have exceptional physical and chemical properties and offer a great number of advanced applications in such fields as energy storage, energy conversion by catalysis, sensors for environmental applications, environment safety and industrial wastewater treatments. They also have interesting medical applications, such as encapsulation of enzymes. The present book covers design, synthesis and preparation of various MOFs, as well as the resulting product characteristics: homogenous morphology, small size dispersion, high thermal stability and desired surface area.

Introduction to Reticular Chemistry
Author : Omar M. Yaghi,Markus J. Kalmutzki,Christian S. Diercks
Publisher : John Wiley & Sons
Release Date : 2019-03-22
ISBN 10 : 3527821104
Pages : 552 pages

A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.

Zeolites and Metal-Organic Frameworks
Author : Vincent Blay,Luis Francisco Bobadilla,Alejandro Cabrera
Publisher : Atlantis Advances in Nanotechnology, Material Science and Energy Technologies
Release Date : 2018-04-11
ISBN 10 : 9789462985568
Pages : 342 pages

Zeolites are natural or synthetic materials with porous chemical structures that are valuable due to their absorptive and catalytic qualities. Metal-Organic Frameworks (MOFs) are manmade organometallic polymers with similar porous structures. This introductory book, with contributions from top-class researchers from all around the world, examines these materials and explains the different synthetic routes available to prepare zeolites and MOFs. The book also highlights how the substances are similar yet different and how they are used by science and industry in situations ranging from fueling cars to producing drugs.

Greenhouse Gases
Author : Bernardo Llamas,Juan Pous
Publisher : BoD – Books on Demand
Release Date : 2016-03-30
ISBN 10 : 9535122738
Pages : 316 pages

Sustainability should be a key component of every process, safeguarding resources and reserves for future generations. This book shows how a responsible use of resources is possible, offering valid technological alternatives to fight climate change. We offer current technologies and valid methods for a wide range of activities: teaching, investigation, work, business and even daily life. We encourage all our readers to join us and become part of the solution to climate change, rather than the problem. After reading this book, we are certain that you will find justified reasons to start your own personal and social awareness campaign in favour of these effective technologies against climate change.

Metal-Organic Frameworks for Chemical Reactions
Author : Anish Khan,Francis Verpoort,Abdullah M. Asiri,Md Enamul Hoque,Anwar L. Bilgrami,Mohammad Azam,Kadiyala Chandra Babu Naidu
Publisher : Elsevier
Release Date : 2021-02-01
ISBN 10 : 0128232625
Pages : 500 pages

Metal-Organic Frameworks for Chemical Reactions: From Organic Transformations to Energy Applications brings together the latest information on MOFs materials, covering recent technology in the field of manufacturing and design. The book covers different aspects of reactions from energy storage and catalysts, including preparation, design and characterization techniques of MOFs material and applications. This comprehensive resource is ideal for researchers and advanced students studying metal-organic frameworks in academia and industry. Metal-organic frameworks (MOFs) are nanoporous polymers made up of inorganic metal focuses connected by natural ligands. These entities have become a hot area of research because of their exceptional physical and chemical properties that make them useful in different fields, including medicine, energy and the environment. Since combination conditions strongly affect the properties of these compounds, it is especially important to choose an appropriate synthetic technique that produces a product with homogenous morphology, small size dispersion, and high thermal stability. Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors Features information on using MOFs as a replacement to conventional engineering materials because they are lightweight, less costly, environmentally-friendly and sustainable

Semiconductor Photocatalysis
Author : Wenbin Cao
Publisher : BoD – Books on Demand
Release Date : 2016-08-24
ISBN 10 : 9535124846
Pages : 676 pages

Photocatalysis is a hot topic because it is an environmentally friendly approach toward the conversion of light energy into chemical energy at mild reaction environments. Also, it is well applied in several major areas such as water splitting, bacterial inactivation, and pollutants elimination, which is a possible solution to energy shortage and environmental issues. The fundamental knowledge and the frontier research progress in typical photocatalytic materials, such as TiO2-based and non-TiO2-based photocatalysts, are included in this book. Methods to improve the photocatalytic efficiency and to provide a hint for the rational design of the new photocatalysts are covered.

Pillared Metal-Organic Frameworks
Author : Lida Hashemi,Ali Morsali
Publisher : John Wiley & Sons
Release Date : 2019-04-30
ISBN 10 : 1119460247
Pages : 378 pages

In the last two decades, metal-organic frameworks (MOFs) have provoked considerable interest due to their potential applications in different fields such as catalysis, gas storage and sensing. The most important advantages of MOFs over other porous materials is the ability of tailoring their pore size, functionality and even the topology of the framework by rational selection of the molecular building blocks. Therefore, many chemists have tried to engineer the structure of MOFs to achieve specific functions. Pillared metal organic frameworks are a class of MOFs composed of inorganic secondary building units (SBUs) and two sets of organic linkers, generally oxygen- and nitrogen-donor ligands. Typically, in the structure of pillared MOFs, the oxygen-donor struts link the metal clusters into a two-dimensional (2D) sheet and the N-donor struts pillar the sheets to generate a three-dimensional (3D) framework. Thus, the construction of MOFs by utilizing two sets of organic linkers could provide an extra possibility for further tuning of MOF’s pore walls. A variety of functional groups including imine, amide and heterocycles were successfully incorporated into bidentate pillar ligand skeleton. Interestingly, by using pillaring linkers with different length, a wide diversity of metal-organic frameworks with tunable pore dimensions and topologies can be obtained. In this book, we introduce pillared metal organic frameworks with their properties and applications.

Nanosensors for Environmental Applications
Author : Satish Kumar Tuteja,Divya Arora,Neeraj Dilbaghi,Eric Lichtfouse
Publisher : Springer Nature
Release Date : 2020-04-28
ISBN 10 : 3030381013
Pages : 302 pages

This book provides a comprehensive overview on the most important types of nanosensor platforms explored and developed in the recent years for efficient detection of environmental/clinical analytes. The chapters cover basic aspects of functioning principles and describe the technologies and challenges of present and future pesticide, metal ions, toxic gases analytical sensing approaches and environmental sensors. Nanosensors are nanoscale miniature devices used for sensing of analyte in ultra-low range. These have gained considerable interest in environmental applications such as environmental chemistry and functionalization approaches, environmental engineering, sustainability, green technology for sensing, environmental health monitoring, pesticide detection, metal and ions detection using electrochemical and wireless sensor.