chemical kinetics

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Chemical Kinetics
Author : Luis G Arnaut,Sebastiao Jose Formosinho,Hugh Burrows
Publisher : Elsevier
Release Date : 2006-12-21
ISBN 10 : 9780080469348
Pages : 562 pages

Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses. * Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations * Of special interest to Industrial Chemistry and Biochemistry

An Introduction to Chemical Kinetics
Author : Michel Soustelle
Publisher : John Wiley & Sons
Release Date : 2013-02-07
ISBN 10 : 1118604229
Pages : 480 pages

This book is a progressive presentation of kinetics of the chemicalreactions. It provides complete coverage of the domain of chemicalkinetics, which is necessary for the various future users in thefields of Chemistry, Physical Chemistry, Materials Science,Chemical Engineering, Macromolecular Chemistry and Combustion. Itwill help them to understand the most sophisticated knowledge oftheir future job area. Over 15 chapters, this book present the fundamentals of chemicalkinetics, its relations with reaction mechanisms and kineticproperties. Two chapters are then devoted to experimental resultsand how to calculate the kinetic laws in both homogeneous andheterogeneous systems. The following two chapters describe the mainapproximation modes to calculate these laws. Three chapters aredevoted to elementary steps with the various classes, theprinciples used to write them and their modeling using the theoryof the activated complex in gas and condensed phases. Threechapters are devoted to the particular areas of chemical reactions,chain reactions, catalysis and the stoichiometric heterogeneousreactions. Finally the non-steady-state processes of combustion andexplosion are treated in the final chapter.

Chemical Kinetics
Author : Kenneth Antonio Connors
Publisher : Wiley-VCH Verlag GmbH
Release Date : 1990
ISBN 10 : 9781560810537
Pages : 480 pages

Chemical Kinetics The Study of Reaction Rates in Solution Kenneth A. Connors This chemical kinetics book blends physical theory, phenomenology and empiricism to provide a guide to the experimental practice and interpretation of reaction kinetics in solution. It is suitable for courses in chemical kinetics at the graduate and advanced undergraduate levels. This book will appeal to students in physical organic chemistry, physical inorganic chemistry, biophysical chemistry, biochemistry, pharmaceutical chemistry and water chemistry all fields concerned with the rates of chemical reactions in the solution phase.

An Introduction to Chemical Kinetics
Author : Claire Vallance
Publisher : Morgan & Claypool Publishers
Release Date : 2017-09-28
ISBN 10 : 1681746670
Pages : 79 pages

The book is a short primer on chemical reaction rates based on a six-lecture first-year undergraduate course taught by the author at the University of Oxford. The book explores the various factors that determine how fast or slowly a chemical reaction proceeds and describes a variety of experimental methods for measuring reaction rates. The link between the reaction rate and the sequence of steps that makes up the reaction mechanism is also investigated. Chemical reaction rates is a core topic in all undergraduate chemistry courses.

Advances in Kinetics and Mechanism of Chemical Reactions
Author : Gennady E. Zaikov,Artur J. M. Valente,Alexei L. Iordanskii
Publisher : CRC Press
Release Date : 2013-03-11
ISBN 10 : 1926895428
Pages : 238 pages

Advances in Kinetics and Mechanism of Chemical Reactions describes the chemical physics and/or chemistry of ten novel material or chemical systems. These ten novel material or chemical systems are examined in the context of various issues, including structure and bonding, reactivity, transport properties, polymer properties, or biological characteristics. This eclectic survey encompasses a special focus on the associated kinetics, reaction mechanism, or other chemical physics properties of these ten chosen material or chemical systems. The most contemporary chemical physics methods and principles are applied to the characterization of the these ten properties. The coverage is broad, ranging from the study of biopolymers to the analysis of antioxidant and medicinal chemical activity, on the one hand, to the determination of the chemical kinetics of not chemical systems and the characterization of elastic properties of novel nanometer scale material systems on the other. The chemical physics methods used to characterize these ten novel systems are state-of-the-art, and the results should be intriguing to those in the chemistry, physics, and nanoscience fields, include scientists engaged in chemical physics research and the polymer chemistry.

Chemical Kinetics and Process Dynamics in Aquatic Systems
Author : PatrickL. Brezonik
Publisher : Routledge
Release Date : 2018-05-08
ISBN 10 : 1351461508
Pages : 784 pages

Chemical Kinetics and Process Dynamics in Aquatic Systems is devoted to chemical reactions and biogeochemical processes in aquatic systems. The book provides a thorough analysis of the principles, mathematics, and analytical tools used in chemical, microbial, and reactor kinetics. It also presents a comprehensive, up-to-date description of the kinetics of important chemical processes in aquatic environments. Aquatic photochemistry and correlation methods (e.g., LFERs and QSARs) to predict process rates are covered. Numerous examples are included, and each chapter has a detailed bibliography and problems sets. The book will be an excellent text/reference for professionals and students in such fields as aquatic chemistry, limnology, aqueous geochemistry, microbial ecology, marine science, environmental and water resources engineering, and geochemistry.

Chemical Reaction Kinetics
Author : Jorge Ancheyta
Publisher : John Wiley & Sons
Release Date : 2017-06-05
ISBN 10 : 1119226651
Pages : 304 pages

A practical approach to chemical reaction kinetics—from basic concepts to laboratory methods—featuring numerous real-world examples and case studies This book focuses on fundamental aspects of reaction kinetics with an emphasis on mathematical methods for analyzing experimental data and interpreting results. It describes basic concepts of reaction kinetics, parameters for measuring the progress of chemical reactions, variables that affect reaction rates, and ideal reactor performance. Mathematical methods for determining reaction kinetic parameters are described in detail with the help of real-world examples and fully-worked step-by-step solutions. Both analytical and numerical solutions are exemplified. The book begins with an introduction to the basic concepts of stoichiometry, thermodynamics, and chemical kinetics. This is followed by chapters featuring in-depth discussions of reaction kinetics; methods for studying irreversible reactions with one, two and three components; reversible reactions; and complex reactions. In the concluding chapters the author addresses reaction mechanisms, enzymatic reactions, data reconciliation, parameters, and examples of industrial reaction kinetics. Throughout the book industrial case studies are presented with step-by-step solutions, and further problems are provided at the end of each chapter. Takes a practical approach to chemical reaction kinetics basic concepts and methods Features numerous illustrative case studies based on the author’s extensive experience in the industry Provides essential information for chemical and process engineers, catalysis researchers, and professionals involved in developing kinetic models Functions as a student textbook on the basic principles of chemical kinetics for homogeneous catalysis Describes mathematical methods to determine reaction kinetic parameters with the help of industrial case studies, examples, and step-by-step solutions Chemical Reaction Kinetics is a valuable working resource for academic researchers, scientists, engineers, and catalyst manufacturers interested in kinetic modeling, parameter estimation, catalyst evaluation, process development, reactor modeling, and process simulation. It is also an ideal textbook for undergraduate and graduate-level courses in chemical kinetics, homogeneous catalysis, chemical reaction engineering, and petrochemical engineering, biotechnology.

Author : Theodore L. Brown,H. Eugene Lemay,Bruce E. Bursten
Publisher : N.A
Release Date : 1999-06-01
ISBN 10 : 9780130963000
Pages : 329 pages

Chemical Kinetics and Dynamics
Author : Jeffrey I. Steinfeld,Joseph Salvadore Francisco,William L. Hase,William L.. Hase
Publisher : Pearson College Division
Release Date : 1999
ISBN 10 :
Pages : 518 pages

This text presents a balanced presentation of the macroscopic view of empirical kinetics and the microscopic molecular viewpoint of chemical dynamics. This second edition includes the latest information, as well as new topics such as heterogeneous reactions in atmospheric chemistry, reactant product imaging, and molecular dynamics of H + H2.

Invariant Manifolds for Physical and Chemical Kinetics
Author : Alexander N. Gorban,Iliya V. Karlin
Publisher : Springer Science & Business Media
Release Date : 2005-02-01
ISBN 10 : 9783540226840
Pages : 496 pages

By bringing together various ideas and methods for extracting the slow manifolds, the authors show that it is possible to establish a more macroscopic description in nonequilibrium systems. The book treats slowness as stability. A unifying geometrical viewpoint of the thermodynamics of slow and fast motion enables the development of reduction techniques, both analytical and numerical. Examples considered in the book range from the Boltzmann kinetic equation and hydrodynamics to the Fokker-Planck equations of polymer dynamics and models of chemical kinetics describing oxidation reactions. Special chapters are devoted to model reduction in classical statistical dynamics, natural selection, and exact solutions for slow hydrodynamic manifolds. The book will be a major reference source for both theoretical and applied model reduction. Intended primarily as a postgraduate-level text in nonequilibrium kinetics and model reduction, it will also be valuable to PhD students and researchers in applied mathematics, physics and various fields of engineering.

Advanced Chemical Kinetics
Author : Muhammad Akhyar Farrukh
Publisher : BoD – Books on Demand
Release Date : 2018-02-21
ISBN 10 : 9535138154
Pages : 224 pages

The book on Advanced Chemical Kinetics gives insight into different aspects of chemical reactions both at the bulk and nanoscale level and covers topics from basic to high class. This book has been divided into three sections: (i) "Kinetics Modeling and Mechanism," (ii) "Kinetics of Nanomaterials," and (iii) "Kinetics Techniques." The first section consists of six chapters with a variety of topics like activation energy and complexity of chemical reactions; the measurement of reaction routes; mathematical modeling analysis and simulation of enzyme kinetics; mechanisms of homogeneous charge compression ignition combustion for the fuels; photophysical processes and photochemical changes; the mechanism of hydroxyl radical, hydrate electron, and hydrogen atom; and acceptorless alcohol dehydrogenation. The understanding of the kinetics of nanomaterials, to bridge the knowledge gap, is presented in the second section. The third section highlights an overview of experimental techniques used to study the mechanism of reactions.

Chemical Kinetics of Gas Reactions
Author : V. N. Kondrat'Ev
Publisher : Elsevier
Release Date : 2016-01-22
ISBN 10 : 1483225186
Pages : 826 pages

Chemical Kinetics of Gas Reactions explores the advances in gas kinetics and thermal, photochemical, electrical discharge, and radiation chemical reactions. This book is composed of 10 chapters, and begins with the presentation of general kinetic rules for simple and complex chemical reactions. The next chapters deal with the experimental methods for evaluating chemical reaction mechanisms and some theories of elementary chemical processes. These topics are followed by discussions on certain class of chemical reactions, including unimolecular, bimolecular, and termolecular reactions. The remaining chapters examine gas reactions, such as molecular collisions, photochemical reactions, chemical reactions in electrical discharge, chain reactions, and combustion. This book will be of value to reaction kinetics engineers and researchers.